Slippage of water past superhydrophobic carbon nanotube forests in microchannels.

نویسندگان

  • P Joseph
  • C Cottin-Bizonne
  • J-M Benoît
  • C Ybert
  • C Journet
  • P Tabeling
  • L Bocquet
چکیده

We present in this Letter an experimental characterization of liquid flow slippage over superhydrophobic surfaces made of carbon nanotube forests, incorporated in microchannels. We make use of a particle image velocimetry technique to achieve the submicrometric resolution on the flow profile necessary for accurate measurement of the surface hydrodynamic properties. We demonstrate boundary slippage on the Cassie superhydrophobic state, associated with slip lengths of a few microns, while a vanishing slip length is found in the Wenzel state when the liquid impregnates the surface. Varying the lateral roughness scale L of our carbon nanotube forest-based superhydrophobic surfaces, we demonstrate that the slip length varies linearly with L in line with theoretical predictions for slippage on patterned surfaces.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Modelling Liquid Flow Through Carbon Nanotubes

In this paper, the structure of a liquid and character of its flow in carbon nanotube is investigated. A review of the literature and the results of experiments show that the simulation of fluid flow for nanoscale systems should be based on the continuum hypothesis taking into account the quantized character of the liquid in the length scale of intermolecular distances. Consideration of the flo...

متن کامل

Self-assembly of carbon nanotube polyhedrons inside microchannels.

Well-defined carbon polyhedrons with faceted morphologies and hollow internal structures made of self-organized multi-walled carbon nanotubes have been fabricated by gas phase catalytic CVD inside microchannels, of which the confined space is critical for the formation of polyhedral structures with hexagonal, heptagonal and octagonal cross-sections that show superhydrophobic properties, with th...

متن کامل

Physicochemical characteristics and droplet impact dynamics of superhydrophobic carbon nanotube arrays.

The physicochemical and droplet impact dynamics of superhydrophobic carbon nanotube arrays are investigated. These superhydrophobic arrays are fabricated simply by exposing the as-grown carbon nanotube arrays to a vacuum annealing treatment at a moderate temperature. This treatment, which allows a significant removal of oxygen adsorbates, leads to a dramatic change in wettability of the arrays,...

متن کامل

A facile and patternable method for the surface modification of carbon nanotube forests using perfluoroarylazides.

A facile patterning method for the functionalization of vertically aligned carbon nanotubes is described. Modification of the surface of nanotube forests with hydrophilic, hydrophobic, or polymerizable small molecules was achieved via UV-triggered attachment of perfluoroarylazides. Multiple functionalizations of the tube surface can be achieved. Macro- and micropatterning of forest substrates w...

متن کامل

Carbon Nanotube Arrays with Tunable Wettability and Their Applications

A combination of UV/ozone and vacuum pyrolysis treatments is introduced to tune the wetting properties of vertically aligned multiwalled carbon nanotube arrays. The UV/ozone treatment renders these arrays superhydrophilic by functionalizing them with oxygenated functional groups. These superhydrophilic arrays have a high affinity to water such that they have a very high specific capacitance in ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Physical review letters

دوره 97 15  شماره 

صفحات  -

تاریخ انتشار 2006